Promotie Giovanni Borsoi: Conservation of calcareous substrates
27 september 2017 12:30 - Locatie: Aula TU Delft - Door: Communication BK
Op 27 september verdedigt Giovanni Borsoi zijn proefschrift 'Nanostructured lime-based materials for the conservation of calcareous substrates'.
Promotor: Prof.ir. R.P.J. van Hees
Copromotor: Dr.ir. B. Lubelli
Nanolimes, i.e. dispersions of lime (Ca(OH)2)nanoparticles in alcohol, have been extensively investigated over the last two decades as consolidation products for calcareous substrates.
The use of nanolimes for consolidation of mural paintings arises from the lack of effective and compatible consolidants for this type of substrates; the use of nanolimes was later extended also to limestone and lime-based mortars, as an alternative for silica-precursor consolidants (e.g. tetraethoxysilan - TEOS), which had shown to have a limited effectiveness and compatibility with calcareous substrates.
Nanolime dispersions are characterized by a very small size of the lime particles, which should provide a proper penetration within the porous network of most building materials. In fact, a homogeneous and in-depth penetration of the consolidant is a crucial requirement when dealing with decayed stones and plasters/renders.
The effectiveness of nanolime dispersions reported in literature appears controversial. Some authors observed a proper penetration and moderate consolidating action, whereas others report poor penetration, poor consolidation action and sometimes the formation of a white haze on the treated surface. There is no agreement concerning the factors affecting the transport and deposition of the lime nanoparticles within a porous network, and the causes of the observed drawbacks are not well understood.
This research investigates and elucidates the behaviour of nanolime products for consolidation of calcareous substrates. Based on the developed knowledge, it proposes and validates a methodology (including solvent modification and application protocol) for improving the consolidation effectiveness of nanolime dispersions, making these a suitable alternative for TEOS products.